Self-assembly of [2]rotaxane exploiting reversible Pt(II)- pyridine coordinate bonds.
نویسندگان
چکیده
A dinuclear self-assembled cationic macrocycle based on Pt(II)-N(pyridine) coordinative bonds and having competitive triflate anions, as metal counterions, is used in the construction of [2]rotaxane and [2]pseudorotaxane architectures assisted by hydrogen bonding. The kinetic lability of the Pt(II)-N(pyridine) coordinative bond controls the dynamics of the [2]rotaxane.
منابع مشابه
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ورودعنوان ژورنال:
- Molecules
دوره 9 5 شماره
صفحات -
تاریخ انتشار 2004